Controlled Synthesis, Dye-fixing Performance and Dye-fixing Mechanisms on Cotton Fabric of Novel Reactive Cationic Copolymers of N,N-Diallyl-3-hydroxy-azetidinium Chloride and Dimethyldiallylammonium Chloride (P(DHAC-DMDAAC)s)

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Contents Vol 65(4)

doi:10.1071/CH11481

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Controlled Synthesis, Dye-fixing Performance and Dye-fixing Mechanisms on Cotton Fabric of Novel Reactive Cationic Copolymers of N,N-Diallyl-3-hydroxy-azetidinium Chloride and Dimethyldiallylammonium Chloride (P(DHAC-DMDAAC)s)

Yikai Yu ^A ^B and Yuejun Zhang ^A ^C

^A School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
^B College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China.
^C Corresponding author. Email: yuyikai1980@163.com

Australian Journal of Chemistry 65(4) 351-365 http://dx.doi.org/10.1071/CH11481
Submitted: 14 December 2011 Accepted: 3 February 2012 Published: 26 April 2012





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Abstract

First, a series of novel reactive cationic copolymers (P(DHAC-DMDAAC)s) of N,N-diallyl-3-hydroxy-azetidinium chloride (DHAC) and dimethyldiallylammonium chloride (DMDAAC) with controlled structures and controlled molecular weights characterized by intrinsic viscosities of 0.11–0.89 dL g^–1 were successfully synthesized by varying the molar ratios of raw materials DHAC to DMDAAC from 1 : 99 to 20 : 80 and increasing initial monomer concentrations from 35 to 55 % with a decrease of initiator amount from 7 to 3 % during polymerization. Second, it was found that the dye-fixing performance of P(DHAC-DMDAAC)s could be further increased by incorporation of 7 % molar content of DHAC units into the main chains of controlled-molecular-weight poly(dimethyldiallylammonium chloride) (PDMDAAC) dye fixatives, and their best dye-fixing performance was better than all the widely used commercial polycationic dye fixatives, indicating that the obtained P(DHAC-DMDAAC)s could be novel useful reactive polycationic dye fixatives for cotton fabric. Last, it was found from studies on dye-fixing mechanisms on cotton fabric by modern analysis techniques that the reactive units (DHAC) of the obtained P(DHAC-DMDAAC)s could form covalent bonds with the hydroxyl groups of cotton (cellulose) to give an ether linkage, resulting in strong interactions of P(DHAC-DMDAAC)s with the cotton fabric as well as the electrostatic forces between the anionic dyes and the basic cationic groups in the polymers to produce water-insoluble colour lakes, for the development of the dye fastness on cotton fabric.

Additional keywords: dye-fixing performance.

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