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Article << Previous     |     Next >>   Contents Vol 65(7)

The First Carbonyl-Substituted Derivative of [Mn2(CO)6(μ-pyS)2]

Md. Saifur Rahman A, Jagodish C. Sarker A, Shishir Ghosh A and Shariff E. Kabir A B

A Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342, Bangladesh.
B Corresponding author. Email: skabir_ju@yahoo.com

Australian Journal of Chemistry 65(7) 796-801 http://dx.doi.org/10.1071/CH12021
Submitted: 18 January 2012  Accepted: 7 February 2012   Published: 19 March 2012
 
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Abstract

Reaction of [Mn2(CO)6(μ-pyS)2] (1) with (Ph3P)2Ni(CO)2 at room temperature affords [Mn2(CO)5(PPh3)(μ-pyS)2] (3) which is the first carbonyl-substituted derivative of 1. A mononuclear complex fac-[Mn(CO)3(PPh3)(κ2-pyS)] (4) is also isolated as a minor product in this reaction. The formation of 3 allows us to propose a different mechanism operating in this reaction. A similar reaction between [Re2(CO)6(μ-pyS)2] (2) and (Ph3P)2Ni(CO)2 gives only mononuclear fac-[Re(CO)3(PPh3)(κ2-pyS)] (5). Both 4 and 5 undergo CO substitution to produce [M(CO)2(PPh3)2(κ2-pyS)] (6, M = Mn; 7, M = Re) when treated with (Ph3P)2Ni(CO)2 in boiling THF. Complex 3 also reacts with further (Ph3P)2Ni(CO)2 at room temperature to give 4 and 6. The molecular structures of 3 and 4 have been established by single crystal X-ray diffraction analyses.





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