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Article << Previous     |     Next >>   Contents Vol 65(12)

CuII Complexes of Isomeric Ligands Derived from 2-Pyridine-carboxaldehyde and m- or p-Xylylenediamine: An Intermolecularly π-Stacked Dinuclear Species and a Trinuclear Circular Helicate that Encapsulates a Chloride Ion

Young Hoon Lee A, Arim Woo A, Mi Seon Won A, Jeong Hwan Cho A, Jack K. Clegg B, Shinya Hayami C, Pierre Thuéry D, Leonard F. Lindoy E and Yang Kim A F

A Department of Chemistry & Advanced Materials, Kosin University, 194, Wachi-Ro, Yeongdo-gu, Busan 606-701, South Korea.
B School of Chemistry and Molecular Biosciences, The University of Queensland, St Lucia, Brisbane, Qld 4072, Australia.
C Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan.
D CEA, IRAMIS, UMR 3299 CEA/CNRS, SIS2M, LCCEf, Bât.125, 91191 Gif-sur-Yvette, France.
E School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia.
F Corresponding author. Email: ykim@kosin.ac.kr

Australian Journal of Chemistry 65(12) 1587-1593 http://dx.doi.org/10.1071/CH12368
Submitted: 4 August 2012  Accepted: 7 September 2012   Published: 31 October 2012


 
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Abstract

Di- and trinuclear CuII complexes [Cu2L1(2,2′-bipyridine)2Cl2]Cl2·11H2O and [Cu3(L2)3Cl3]Cl3·1.25MeOH·4H2O incorporating the isomeric Schiff base ligands 1,1′-(1,4-phenylene)bis(N-(pyridin-2-ylmethylene)methanamine) (L1) and 1,1′-(1,4-phenylene)bis(N-(pyridin-2-ylmethylene)methanamine) (L2), each incorporating two separated α-diimine coordination domains, have been synthesised and their X-ray crystal structures and variable temperature magnetic properties determined. The X-ray crystal structure of [Cu2L1(2,2′-bipyridine)2Cl2]Cl2·11H2O shows that each CuII centre is bound to two nitrogen atoms from L1, two from a bipyridine ligand, and a chloride anion. Intramolecular π-stacking interactions are present between the central phenyl ring of L1 and both rings of each bipyridine ligand. The structure of [Cu3(L2)3Cl3]Cl3·1.25MeOH·4H2O shows an unusual trinuclear circular helicate arrangement with approximate C3-symmetry. A chloride anion is encapsulated in the structure being bound by six non-classical hydrogen bond interactions. Variable temperature magnetic susceptibility measurements indicated the presence of weak antiferromagnetic behaviour for [Cu2L1(2,2′-bipyridine)2Cl2]Cl2·11H2O and weak ferromagnetic behaviour for [Cu3(L2)3Cl3]Cl3·1.25MeOH·4H2O.





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