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RESEARCH ARTICLE
Contents Vol 68(6)

Distinct 3D CdII Coordination Polymers with 1,2-Naphthalenedicarboxylate Regulated by Dipyridyl Co-Ligands with Different Spacers

Zhuo-Wei Wang A , Hui Zhao A , Min Hu A and Chun-Sen Liu A B
+ Author Affiliations
- Author Affiliations

A Zhengzhou University of Light Industry, Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou, Henan 450002, China.

B Corresponding author. Email: chunsenliu@zzuli.edu.cn

Australian Journal of Chemistry 68(6) 906-911 https://doi.org/10.1071/CH14470
Submitted: 25 July 2014  Accepted: 28 August 2014   Published: 18 November 2014

Abstract

Two distinct three-dimensional (3D) CdII coordination polymers with 1,2-naphthalenedicarboxylate (ndc2–) and dipyridyl co-ligands have been synthesized under hydrothermal conditions. Interestingly, the slight difference in the two 4,4′-dipyridyl building blocks, namely, 1,2-bi(4-pyridyl)ethane (bpp) and 1,2-bi(4-pyridyl)ethene (bpe) with C–C or C=C spacers, results in the significant structural divergence of the resultant coordination polymers. Structural analysis reveals that complexes [Cd(ndc)(bpp)(H2O)]n (1) and {[Cd5(ndc)4(bpe)2(OH)2](H2O)1.5}n (2) are constructed by discrete metal–carboxylate dimeric units and metal–carboxylate chains, respectively, which are further extended by bpp or bpe linkers to form the inclined interpenetrated two-dimensional (2D)→3D network for 1 and the 3D porous framework for 2. This result reveals that the flexibility of auxiliary ligands plays an important role in the structural assemblies of coordination networks. The thermal and luminescence properties of both complexes were also investigated in solid state.


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