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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH FRONT

Chemistry of the Synthetic Strigolactone Mimic GR24*,**

Liam J. Bromhead A , Jason Smith B and Christopher S. P. McErlean A C
+ Author Affiliations
- Author Affiliations

A School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia.

B School of Physical Sciences (Chemistry), University of Tasmania, Hobart, Tas. 7001, Australia.

C Corresponding author. Email: christopher.mcerlean@sydney.edu.au

Australian Journal of Chemistry 68(8) 1221-1227 https://doi.org/10.1071/CH15298
Submitted: 25 May 2015  Accepted: 11 June 2015   Published: 9 July 2015

Abstract

This research paper describes a second-generation, enantioselective synthesis of (+)-GR24. This new strategy circumvents the need for ozonolysis, which may not be suitable for reactions performed on scale. This flexible new approach is then used to synthesise a novel bromo-GR24 analogue. Finally, the optimal solvent for making GR24 stock solutions is identified.


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