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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Novel MII (M = Mn, Fe, Co, Ni) Coordination Assemblies Based on 2-(((1-(Pyridin-n-ylmethyl)-1H-1,2,3-triazol-4-yl)methyl)thio)pyridine Ligands

Lu Jiang A B , Zhe Wang B , Shi-Qiang Bai B C , Xian Jun Loh B C and T. S. Andy Hor A B C
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Republic of Singapore.

B Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, #08-03, Innovis, Singapore 138634, Republic of Singapore.

C Corresponding authors. Email: bais@imre.a-star.edu.sg; lohxj@imre.a-star.edu.sg; andyhor@nus.edu.sg

Australian Journal of Chemistry 69(6) 645-651 https://doi.org/10.1071/CH15362
Submitted: 18 June 2015  Accepted: 11 October 2015   Published: 19 November 2015

Abstract

Three novel 1D coordination polymers [M(L1)2(OH2)2(ClO4)2]n (M = Mn (1), Co (2)) and [Ni(L1)2(OH2)2(NO3)2]n (3), and two mononuclear complexes [Fe(L2)2(MeOH)2(ClO4)2] (4) and [Co(L2)2(OH2)2(ClO4)2] (5) were prepared from 2-(((1-(pyridin-n-ylmethyl)-1H-1,2,3-triazol-4-yl)methyl)thio)pyridine ligands (n = 4 (L1), and 2 (L2)). The complexes 15 were characterised by single-crystal X-ray diffraction (XRD), powder XRD, thermogravimetric analysis, elemental analysis, infrared, and electrospray ionisation mass spectrometry analyses. The complexes 15 showed good purity and thermal stability. The structural outcome of 13 is driven by the double and open-bridging coordination mode preference of the spacer L1 which favours the formation of polymeric 18-member metallomacrocycles. Use of an isomeric L2 with different picolyl nitrogen orientation, which favours chelate formation, resulted in mononuclear complexes 4 and 5. This work demonstrates a simple but powerful spacer-directed strategy to define and construct coordination frameworks tuned by different metal characters and hybrid 1,2,3-triazoles.


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