Catalytic deuterium exchange reactions with organics. XIII. Characteristic reactions of the Group VIII transition metals

doi:10.1071/CH9651003

Catalytic deuterium exchange reactions with organics. XIII. Characteristic reactions of the Group VIII transition metals

JL Garnett and WA Sollich

Australian Journal of Chemistry 18(7) 1003 - 1008
Published: 1965

Abstract

Activation procedures and hydrogen exchange reactions with six Group VIII transition metal catalysts (Pt, Pd, Ru, Rh, Ir, Ni) are reported for three characteristic reaction systems: (i) deuterium oxide/benzene, (ii) deuterium oxide/naphthalene, and (iii) deuterium oxide/n-octane. Results of these exchange reactions indicate that both π-complex adsorption and the dissociative π-complex substitution mechanism previously established for platinum are applicable to other Group VIII transition metal catalysts. For general catalytic labelling with isotopic hydrogen, platinum was found to be the most efficient of the catalysts investigated.