Chemistry of pyrrolic compounds. XLVI. Benzyl β-keto propionate porphyrins: a new synthesis of deoxophylloerythroaetioporphyrin and harderoporphyrin
IA Chaudhry, PS Clezy and AH Mirza
Australian Journal of Chemistry
33(5) 1095 - 1104
Porphyrins with benzyl β-keto propionate side chains have been prepared by condensation of the appropriate porphyrin acid chloride with the magnesium chelate of the enolate form of benzyl hydrogen malonate. Intermediates of this class have been used in the synthesis of deoxophylloery-throaetioporphyrin and harderoporphyrin.
Full text doi:10.1071/CH9801095
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