Diorganotin(IV) derivatives of monothio β-diketones
SK Saini, VD Gupta, RC Mehrotra and RP Tripathi
Australian Journal of Chemistry
33(5) 1137 - 1141
Diorganotin(IV) derivatives of monothio β-diketones of the general formula R2Sn(R'CSCHCOR')2 (R = Me, Bu, Ph; R' = Ph, Me; R'' = Ph, p-FC6H4, 2-F,4-OMeC6H3) have been synthesized by the reactions of R2SnCl2 or R2SnO with monothio β-diketones. Complexes of the type, SnX2(R'CSCHCOR')2 (X = Cl, Br, OAc), have also been synthesized. These compounds have been characterized by element analyses as well as by i.r., 1H n.m.r., and Mossbauer spectra. Ebullioscopic molecular weight determinations show them to be monomeric in benzene.
Full text doi:10.1071/CH9801137
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