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Australian Journal of Chemistry Australian Journal of Chemistry Society
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RESEARCH ARTICLE

Structural Chemistry of the Platinum Group Metals: the Palladacyclopentane Complex (Butane-1,4-diyl)(N,N,N',N'-tetramethylethylenediamine)palladium(II)

AJ Canty, BW Skelton, PR Traill and AH White

Australian Journal of Chemistry 47(11) 2119 - 2122
Published: 1994

Abstract

A single-crystal X-ray structure determination of the reagent (butane-1,4-diyl)(N,N,N′,N′- tetramethylethylenediamine)palladium(II) has shown that crystals are orthorhombic, Pbca, a 15.832(3), b 14.128(9), c 11.451(3) Ǻ, Z 8. The square planar complex has puckered PdCH2CH2CH2CH2 and PdNMe2CH2CH2NMe2 rings in which the outer carbon atoms deviate by c. ±0.35 Ǻ from the 'PdC2N2' mean plane.

https://doi.org/10.1071/CH9942119

© CSIRO 1994

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