Synthesis and Functional Properties of Star-Burst Dendrimers that Contain Carbazole as Peripheral Edges and Triazine as a Central Core

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doi:10.1071/CH07038

Synthesis and Functional Properties of Star-Burst Dendrimers that Contain Carbazole as Peripheral Edges and Triazine as a Central Core

Mo Jun Xiong ^A, Zhong Hui Li ^B ^D, Man Shing Wong ^C

^A West China School of Pharmacy, Sichuan University, Chengdu 610041, Sichuan Province, China.
^B Department of Chemistry, Sichuan College of Education, Chengdu 610041, Sichuan Province, China.
^C Department of Chemistry, Hong Kong Baptist University, Hong Kong SAR, China.
^D Corresponding author. Email: zhonghli@sohu.com





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Australian Journal of Chemistry 60(8) 603–607 http://dx.doi.org/10.1071/CH07038
Submitted: 4 February 2007 Accepted: 1 May 2007 Published online: 9 August 2007

Abstract

With the aim of combining the electron and hole-transporting moieties into one molecule and to continue our investigation into the structure–property correlations of dendrimers, two novel star-burst dendrimers 1 and 2 constructed with carbazoles as the peripheral hole-transporting moieties and one triazine moiety as an electron-transporting central core, have been synthesized. The convergent synthetic approach uses palladium-catalyzed Suzuki cross-coupling as a key reaction. Their functional properties have also been investigated.