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Australian Journal of Chemistry
  An international journal for chemical science
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Biomimetic Preparation of the Racemic Modifications of the Stilbenolignan Aiphanol and Three Congeners

Satish Chand A and Martin G. Banwell A B

A Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia.
B Corresponding author. Email: mgb@rsc.anu.edu.au


Abstract

A chromatographically separable mixture of the racemic modification, (±)-1, of the stilbenolignan (–)-aiphanol and congeners (±)-24 has been generated by a silver(I)-mediated and potentially biomimetic oxidative coupling of piceatannol (5) with sinapic alcohol (6).

Australian Journal of Chemistry 60(4) 243–250    doi:10.1071/CH07044
Submitted: 13 February 2007    Accepted: 12 March 2007    Published: 26 April 2007





   
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