End Group Reactions of RAFT-Prepared (Co)Polymers

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doi:10.1071/CH11152

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End Group Reactions of RAFT-Prepared (Co)Polymers

M. Alyse Harvison ^A , Peter J. Roth ^A , Thomas P. Davis ^A and Andrew B. Lowe ^A ^B

^A Centre for Advanced Macromolecular Design (CAMD), School of Chemical Engineering, University of New South Wales, Kensington, Sydney, NSW 2052, Australia.
^B Corresponding author. Email: a.lowe@unsw.edu.au

Australian Journal of Chemistry 64(8) 992-1006 http://dx.doi.org/10.1071/CH11152
Submitted: 19 April 2011 Accepted: 18 May 2011 Published: 19 August 2011





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Abstract

This review highlights the chemistry of thiocarbonylthio groups with an emphasis on chemistry conducted at ω or α and ω chain-ends in copolymers prepared by reversible addition–fragmentation chain-transfer (RAFT) radical polymerization. We begin by giving a general overview of reactions associated with the thiocarbonylthio groups, followed by examples associated with macromolecular thiols.

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