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Contents Vol 65(7)

Hydrated Lanthanoid Complexes of 5-(2′-Pyridyl)tetrazole Formed in the Presence of Dimethyl Sulfoxide*

Daniel D'Alessio A , Louise E. Karagiannidis A B , Brian W. Skelton C , Massimiliano Massi A and Mark I. Ogden A D
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Curtin University, GPO Box U 1987, Perth, WA 6845, Australia.

B Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.

C Centre for Microscopy, Characterisation and Analysis, M313, University of Western Australia, Perth, WA 6009, Australia.

D Corresponding author. Email: m.ogden@curtin.edu.au

Australian Journal of Chemistry 65(7) 819-822 https://doi.org/10.1071/CH12031
Submitted: 19 January 2012  Accepted: 18 February 2012   Published: 2 April 2012

Abstract

Reaction of DMSO solvates of lanthanoid nitrates or perchlorates with 5-(2′-pyridyl)tetrazole (pytz) and triethylamine in organic solvents resulted in the unexpected crystallization of hydrates, rather than DMSO solvates. This was confirmed by the structural characterization of [Eu(pytz)3(H2O)3]. Decreasing the metal:ligand ratio in the reaction mixture resulted in the crystallization of a complex salt formulated as [Y(pytz)2(H2O)4](pytz)·(Hpytz)·4H2O; once again DMSO was absent from the product. Interestingly, the omission of base from one reaction resulted in the serendipitous crystallization of Hpytz in a zwitterionic form, unlike the neutral ligand structure reported previously.


References

[1]  R. J. Herr, Bioorg. Med. Chem. 2002, 10, 3379.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD38Xms12jurY%3D&md5=53169518becb926b0d17ef5adf0593a8CAS |

[2]  S. Stagni, S. Colella, A. Palazzi, G. Valenti, S. Zacchini, F. Paolucci, M. Marcaccio, R. Q. Albuquerque, L. De Cola, Inorg. Chem. 2008, 47, 10509.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXht1OjtLrO&md5=ea6314e535297f0066358bd6ca2a1ea8CAS |

[3]  M. V. Werrett, D. Chartrand, J. D. Gale, G. S. Hanan, J. G. MacLellan, M. Massi, S. Muzzioli, P. Raiteri, B. W. Skelton, M. Silberstein, S. Stagni, Inorg. Chem. 2011, 50, 1229.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXht1ems7s%3D&md5=ee85db7ae248eb061e5488d107ccec8eCAS |

[4]  H. Zhao, Z. R. Qu, H. Y. Ye, R. G. Xiong, Chem. Soc. Rev. 2008, 37, 84.
         | Crossref | GoogleScholarGoogle Scholar |

[5]  P. C. Andrews, T. Beck, B. H. Fraser, P. C. Junk, M. Massi, Polyhedron 2007, 26, 5406.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2sXht1Giu73F&md5=ad8b1126363fd5f0988d96543e0ff6d6CAS |

[6]  P. C. Andrews, P. C. Junk, M. Massi, M. Silberstein, Chem. Commun. (Camb.) 2006, 3317.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD28XnvVSqsLc%3D&md5=cea92f3317cbece54d92fe60d6caf0b4CAS |

[7]  Y.-S. Zhou, D.-H. Xu, L.-J. Zhang, Chem. Res. Chin. Univ. 2010, 26, 866.
         | 1:CAS:528:DC%2BC3cXhsF2jsLrJ&md5=071cab6f077d88ec044c2cc79ad64680CAS |

[8]  A. Facchetti, A. Abbotto, L. Beverina, S. Bradamante, P. Mariani, C. L. Stern, T. J. Marks, A. Vacca, G. A. Pagani, Chem. Commun. (Camb.) 2004, 1770.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2cXmtVWgsrs%3D&md5=6a44d2e9da98a302410845b9b0790b1dCAS |

[9]  C. R. Driscoll, B. L. Reid, M. J. McIldowie, S. Muzzioli, G. L. Nealon, B. W. Skelton, S. Stagni, D. H. Brown, M. Massi, M. I. Ogden, Chem. Commun. (Camb.) 2011, 47, 3876.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXjt1Snsbc%3D&md5=ecae6c6b407bd733eadd89f8bc576ab1CAS |

[10]  P. C. Andrews, T. Beck, B. H. Fraser, P. C. Junk, M. Massi, B. Moubaraki, K. S. Murray, M. Silberstein, Polyhedron 2009, 28, 2123.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXnt1ajsbw%3D&md5=3373fb3f94532d457a6831e64f3d2cfaCAS |

[11]  P. C. Andrews, G. B. Deacon, R. Frank, B. H. Fraser, P. C. Junk, J. G. MacLellan, M. Massi, B. Moubaraki, K. S. Murray, M. Silberstein, Eur. J. Inorg. Chem. 2009, 744.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXjt12jur0%3D&md5=2dea40f9f04ce04aac8719b33486ba20CAS |

[12]  A. Dossing, Eur. J. Inorg. Chem. 2005, 1425.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXktVCmsL4%3D&md5=6e6e3aa02b184bd07749f141b521ed0cCAS |

[13]  L. I. Semenova, B. W. Skelton, A. H. White, Aust. J. Chem. 1996, 49, 997.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK28XntlyrsLc%3D&md5=56881ff1c834e1cfffdfc76d15edaf2bCAS |

[14]  E. J. Chan, B. G. Cox, J. M. Harrowfield, M. I. Ogden, B. W. Skelton, A. H. White, Inorg. Chim. Acta 2004, 357, 2365.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2cXksVGhs7s%3D&md5=3f7fb0d736f6947f3f9928e76f4d82b4CAS |

[15]  Z. Asfari, J. M. Harrowfield, M. I. Ogden, J. Vicens, A. H. White, Angew. Chem. Int. Edit. 1991, 30, 854.
         | Crossref | GoogleScholarGoogle Scholar |

[16]  S. Fleming, C. D. Gutsche, J. M. Harrowfield, M. I. Ogden, B. W. Skelton, D. F. Stewart, A. H. White, Dalton Trans. 2003, 3319.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD3sXmsVKmtLw%3D&md5=f986bd2432321ac7da6f63193d5e882aCAS |

[17]  J. M. Harrowfield, M. I. Ogden, A. H. White, Aust. J. Chem. 1991, 44, 1237.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaK38XltVakug%3D%3D&md5=b63985abdf09171efe814c349366971fCAS |

[18]  I. Sanchez-Lombardo, C. M. Andolina, J. R. Morrow, A. K. Yatsimirsky, Dalton Trans. 2010, 39, 864.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1MXhsF2isLbJ&md5=80d1aed05164539ac0d8298164eea580CAS |

[19]  P. Di Bernardo, A. Melchior, M. Tolazzi, P. L. Zanonato, Coord. Chem. Rev. 2012, 256, 328.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BC3MXhsFarsLjJ&md5=ebdf98425a5f501043f74a58d59af07bCAS |

[20]  I. Sanchez-Lombardo, A. K. Yatsimirsky, Inorg. Chem. 2008, 47, 2514.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD1cXjtVShsrw%3D&md5=480a4ef3de49c60cddc303f83ea813a6CAS |

[21]  F. Tanaka, Y. Kawasaki, S. Yamashita, J. Chem. Soc., Faraday Trans. I 1988, 84, 1083.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaL1cXhslCmt7Y%3D&md5=e81f0684586646ce3bb1f76cf5761e11CAS |

[22]  A. T. Rizk, C. A. Kilner, M. A. Halcrow, CrystEngComm 2005, 7, 359.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DC%2BD2MXltlOqsbg%3D&md5=0659b7923903aaa2916912b7e1ce383eCAS |

[23]  V. N. Krishnamurthy, S. Soundararajan, J. Inorg. Nucl. Chem. 1967, 29, 517.
         | Crossref | GoogleScholarGoogle Scholar | 1:CAS:528:DyaF2sXmtFersQ%3D%3D&md5=6d0cdb47f1d96728f81cd7dd9ddfb149CAS |

[24]  G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112.
         | 1:CAS:528:DC%2BD2sXhsVGhurzO&md5=9b979ddbd87a78d6c18caa3d7e8cf709CAS |