The Chemistry of Transition Metal Ethyne-1,2-diyl Complexes

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doi:10.1071/CH12190

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The Chemistry of Transition Metal Ethyne-1,2-diyl Complexes*

Christopher S. Griffith ^A ^B and George A. Koutsantonis ^A ^C

^A Chemistry, M313, School of Chemistry and Biochemistry, University of Western Australia, Crawley, Perth, WA 6009, Australia.
^B Present address: ANSTO Minerals, Australian Nuclear Science and Technology Organisation, Locked Bag 2001 Kirrawee DC, NSW 2232, Australia.
^C Corresponding author. Email: george.koutsantonis@uwa.edu.au

Australian Journal of Chemistry 65(7) 698-722 http://dx.doi.org/10.1071/CH12190
Submitted: 10 April 2012 Accepted: 18 June 2012 Published: 2 August 2012





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Abstract

The chemistry and reactivity of ethyne-1,2-diyl compounds, L_nM–CC–ML_n, is reviewed. These complexes are simple analogues of organic alkynes, or dimetalloalkynes, and there appears to be no general route to the preparation of these complexes, except perhaps using acid/base methodology. Reactivity patterns, in general, mimic those of simple organic alkynes but have the added dimension of reactive M–C(sp) bonds that sometimes participate in the formation of multimetallic compounds with metal electrophiles.

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