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Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks
Zilu
Chen A B,
Chuanbing
Zhang A,
Xianlin
Liu A,
Zhong
Zhang A and
Fupei
Liang A B
A
Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering of Guangxi Normal University, Guilin 541004, P. R. China.
B
Corresponding authors. Email: zlchen_gxnu@yahoo.com.cn; fliangoffice@yahoo.com
Australian Journal of Chemistry
65(12)
1662-1666 http://dx.doi.org/10.1071/CH12270
Submitted: 1 June 2012 Accepted: 21 August 2012 Published:
13
September
2012
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Abstract
A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas. 
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