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Article << Previous     |     Next >>   Contents Vol 66(1)

Carboxylate-Bridged Dinuclear Dy2 Single-Molecule Magnets: Synthesis, Structure, and Magnetic Studies

Yu-mei Song A , Feng Luo A B , Yan Zhu A , Xiao-zhao Tian A and Gong-ming Sun A

A College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou, 344000 Jiangxi, China.
B Corresponding author. Email: ecitluofeng@163.com

Australian Journal of Chemistry 66(1) 98-104 http://dx.doi.org/10.1071/CH12377
Submitted: 13 August 2012  Accepted: 16 September 2012   Published: 22 October 2012


 
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Abstract

In this work, the synthesis, structure, and magnetic studies of three dinuclear Dy2 compounds, namely Dy2(bpy)2(L)6 (1), Dy2(phen)2(L)6 (2), Dy2(μ-H2O)2(bpy)2(L)6 (3) are reported in detail, where HL, phen, and bpy are 4-chlorobenzoic acid, 1,10-phenanthroline, and 2,2′-bipyridine. Magnetic studies reveal the intramolecular ferromagnetic interaction and single-molecule magnetic properties of these compounds. The fine-tuned single-molecule magnet properties of compounds 13, mainly due to the difference of the coordination geometry of DyIII ions, are highlighted.





References

[1]  (a) J. Tang, I. J. Hewitt, N. T. Madhu, G. Chastanet, W. Wernsdorfer, C. E. Anson, C. Benelli, R. Sessoli, A. K. Powell, Angew. Chem. Int. Ed. 2006, 45, 1729.
         | CrossRef | CAS |
      (b) P.-H. Lin, T. J. Burchell, R. Clérac, M. Murugesu, Angew. Chem. Int. Ed. 2008, 47, 8848.
         | CrossRef |
      (c) I. J. Hewitt, J. Tang, N. T. Madhu, C. E. Anson, Y. Lan, J. Luzon, Angew. Chem. Int. Ed. 2010, 49, 6352.
         | CrossRef |

[2]  R. A. Layfield, J. J. W. McDouall, S. A. Sulway, F. Tuna, D. Collison, R. E. P. Winpenny, Chem. – Eur. J. 2010, 16, 4442.
         | CrossRef | CAS |

[3]  R. Sessoli, A. K. Powell, Coord. Chem. Rev. 2009, 253, 2328.
         | CrossRef | CAS |

[4]  Y. Z. Zheng, Y. H. Lan, W. Wernsdorfer, C. E. Anson, A. K. Powell, Chem. – Eur. J. 2009, 15, 12566.
         | CrossRef | CAS |

[5]  N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Phys. Chem. B 2004, 108, 11265.
         | CrossRef | CAS |

[6]  (a) N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Am. Chem. Soc. 2003, 125, 8694.
         | CrossRef | CAS |
      (b) N. Ishikawa, M. Sugita, W. Wernsdorfer, Angew. Chem. Int. Ed. 2005, 44, 2931.
         | CrossRef |
      (c) N. Ishikawa, M. Sugita, W. Wernsdorfer, J. Am. Chem. Soc. 2005, 127, 3650.
         | CrossRef |

[7]  S. D. Jiang, B. W. Wang, G. Su, Z. M. Wang, S. Gao, Angew. Chem. Int. Ed. 2010, 49, 7448.
         | CrossRef | CAS |

[8]  G. F. Xu, Q. L. Wang, P. Gamez, Y. Ma, R. Clérac, J. K. Tang, S. P. Yan, P. Cheng, D. Z. Liao, Chem. Commun. 2010, 1506.
         | CrossRef | CAS |

[9]  J. Long, F. Habib, P. Lin, I. Korobkov, G. Enright, L. Ungur, W. Wernsdorfer, L. F. Chibotaru, M. Murugesu, J. Am. Chem. Soc. 2011, 133, 5319.
         | CrossRef | CAS |

[10]  M. G. B. Drew, Coord. Chem. Rev. 1977, 24, 179.
         | CrossRef | CAS |

[11]  (a) F. Luis, M. J. Martínez-Pérez, O. Montero, E. Coronado, S. Cardona-Serra, C. Martí-Gastaldo, J. M. Clemente-Juan, J. Sesé, D. Drung, T. Schurig, Phys. Rev. B 2010, 82, 060403.
         | CrossRef |
      (b) R. Giraud, W. Wernsdorfer, A. M. Tkachuk, D. Mailly, B. Barbara, Phys. Rev. Lett. 2001, 87, 057203.
         | CrossRef |
      (c) W. Wernsdorfer, T. Ohm, C. Sangregorio, R. Sessoli, D. Mailly, C. Paulsen, Phys. Rev. Lett. 1999, 82, 3903.
         | CrossRef |
      (d) D. E. Freedman, W. H. Harman, T. D. Harris, G. J. Long, C. J. Chang, J. R. Long, J. Am. Chem. Soc. 2010, 132, 1224.
         | CrossRef |

[12]  (a) J. D. Rinehart, M. Fang, W. J. Evans, J. R. Long, Nat. Chem. 2011, 3, 538.
         | CrossRef | CAS |
      (b) J. D. Rinehart, M. Fang, W. J. Evans, J. R. Long, J. Am. Chem. Soc. 2011, 133, 14236.
         | CrossRef |

[13]  (a) Y. Wang, X. Li, T. W. Wang, Y. Song, X. Z. You, Inorg. Chem. 2010, 49, 969.
         | CrossRef | CAS |
      (b) Y. G. Huang, X. T. Wang, F. L. Jiang, S. Gao, M. Y. Wu, Q. Gao, W. Wei, M. C. Hong, Chem. – Eur. J. 2008, 14, 10340.
         | CrossRef |
      (c) Y. Z. Zheng, Y. Lan, W. Wernsdorfer, C. E. Anson, A. K. Powell, Chem. – Eur. J. 2009, 15, 12566.
         | CrossRef |

[14]  (a) A. Yamashita, A. Watanabe, S. Akine, T. Nabeshima, M. Nakano, T. Yamamura, T. Kajiwara, Angew. Chem. Int. Ed. 2011, 50, 4016.
         | CrossRef | CAS |
      (b) A. Watanabe, A. Yamashita, M. Nakano, T. Yamamura, T. Kajiwara, Chem. – Eur. J. 2011, 17, 7428.
         | CrossRef |

[15]  (a) R. J. Blagg, C. A. Muryn, E. J. L. McInnes, F. Tuna, R. E. P. Winpenny, Angew. Chem. Int. Ed. 2011, 50, 6530.
         | CrossRef | CAS |
      (b) S. D. Jiang, B. W. Wang, H. L. Sun, Z. M. Wang, S. Gao, J. Am. Chem. Soc. 2011, 133, 4730.
         | CrossRef |
      (c) R. Ohtani, K. Yoneda, S. Furukawa, N. Horike, S. Kitagawa, A. B. Gaspar, M. C. Muñoz, J. Real, A. M. Ohba, J. Am. Chem. Soc. J. 2011, 133, 8600.
         | CrossRef |

[16]  (a) L. Thomas, F. Lionti, R. Ballou, D. Gatteschi, R. Sessoli, B. Barbara, Nature 1996, 383, 145.
         | CrossRef | CAS |
      (b) Y. M. Song, F. Luo, M. B. Luo, Z. W. Liao, G. M. Sun, X. Z. Tian, Y. Zhu, Z. J. Yuan, S. J. Liu, W. Y. Xu, X. F. Feng, Chem. Commun. 2012, 1006.
         | CrossRef |
      (c) F. Luo, Z. W. Liao, Y. M. Song, H. X. Huang, X. Z. Tian, G. M. Sun, Y. Zhu, Z. J. Yuan, M. B. Luo, S. J. Liu, W. Y. Xu, X. F. Feng, Dalton Trans. 2011, 40, 12651.
         | CrossRef |
      (d) Y. Zhu, F. Luo, Y. M. Song, H. X. Huang, G. M. Sun, X. Z. Tian, Z. J. Yuan, Z. W. Liao, M. B. Luo, S. J. Liu, W. Y. Xu, X. F. Feng, Dalton Trans. 2012, 41, 6749.
         | CrossRef |
      (e) F. Luo, Y. M. Song, H. X. Huang, X. Z. Tian, G. M. Sun, Y. Zhu, X. F. Feng, Aust. J. Chem. 2012, 65, 1436.
         | CrossRef |

[17]  (a) P. H. Lin, T. J. Burchell, R. Clérac, M. Murugesu, Angew. Chem. Int. Ed. 2008, 47, 8848.
         | CrossRef | CAS |
      (b) S. D. Jiang, B. W. Wang, G. Su, Z. M. Wang, S. Gao, Angew. Chem. Int. Ed. 2010, 49, 7448.
         | CrossRef |
      (c) D. E. Freedman, W. H. Harman, T. D. Harris, G. J. Long, C. J. Chang, J. Am. Chem. Soc. 2010, 132, 1224.
         | CrossRef |


   
 


    
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