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RESEARCH ARTICLE
Contents Vol 69(4)

Three 3d–4f Tetranuclear Complexes Based on 2,3,5-Trichlorobenzoic Acid: Syntheses, Structures, and Magnetic Properties

Yu Zhang A and Ji-Min Zheng A B
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Nankai University, Tianjin 300071, China.

B Corresponding author. Email: jmzheng@nankai.edu.cn

Australian Journal of Chemistry 69(4) 446-450 https://doi.org/10.1071/CH15338
Submitted: 9 June 2015  Accepted: 27 August 2015   Published: 26 October 2015

Abstract

The solvothermal reactions of 2,3,5-trichlorobenzoic acid (HL) 2,2′-bipyridine (bipy), CoCl2·6H2O, and Ln2O3 afforded three novel 3d–4f tetranuclear complexes Co2Ln2(L)10(bipy)2 (Ln = Dy 1, Ho 2, and Er 3), which have been characterized by single-crystal X-ray diffraction, infrared spectroscopy, and element analyses. Complexes 1–3 crystallize in the triclinic space group P1, and the completely deprotonated L ligands possess μ2 : η2, η1 and μ2 : η1, η1 coordination modes to bridge adjacent metal ions, which further connect into 2D layers by hydrogen bonds. Magnetic studies indicate ferromagnetic interactions between adjacent metal ions in complexes 1 and 3.


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