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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Free radicals in the reaction between t-butyl hydroperoxide and titanous ion: Some observations by electron spin resonance spectrometry

MFR Mulcahy, JR Steven and JC Ward

Australian Journal of Chemistry 18(8) 1177 - 1181
Published: 1965

Abstract

The reaction between t-butyl hydroperoxide and titanous ion in aqueous solution produces free methyl radicals detectable by electron spin resonance spectrometry (Dixon and Norman). However, the presence of titanous ion in concentrations greater than 0.01M broadens the spectrum of the methyl radical, causing it effectively to disappear at titanous concentrations greater than 0.1M. At hydroperoxide concentrations above 0.25M t-butyl peroxy radicals (identified by a strong single-line spectrum with g-value 2.0136) are produced by the reaction            R. + (CH3)3COOH → RH + (CH3)3COO. Their concentration reaches a maximum about 1 sec after the concentration of the methyl radicals has fallen to an undetectable value and their half-life (≈ 5 sec) is about ten times that of the methyl radicals.

https://doi.org/10.1071/CH9651177

© CSIRO 1965

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