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Article << Previous     |     Next >>   Contents Vol 32(6)

Chiral Shielding in Nuclear Magnetic Resonance Spectroscopy

PJ Stiles

Australian Journal of Chemistry 32(6) 1375 - 1377
Published: 1979

Abstract

A novel van der Waals shielding mechanism is discussed which contributes to the magnetic shielding non-equivalence of optical isomers of one chiral species in the presence of a second optically active species. It is more direct than standard mechanisms which invoke stereospecific association of the interacting molecules but appears to be of marginal experimental significance.



Full text doi:10.1071/CH9791375

© CSIRO 1979

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