Composition profile of oxygenated organic compounds and inorganic ions in PM2.5 in Hong Kong
Yun Chun Li A B and Jian Zhen Yu A C DA Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.
B School of Science, Sichuan Agricultural University, Sichuan Province, 625014, China.
C Division of Environment, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.
D Corresponding author. Email: chjianyu@ust.hk
Environmental Chemistry 7(4) 338-349 https://doi.org/10.1071/EN09167
Submitted: 31 December 2009 Accepted: 30 June 2010 Published: 20 August 2010
Environment context. Oxygenated organic compounds are active constituents in ambient aerosols, affecting their hygroscopic properties and other interactions with water. We have measured 29 oxygenated organic compounds, together with inorganic ions and other major aerosol constituents, in ambient samples collected under various synoptic conditions in Hong Kong. These composition profiles of water-soluble matter provide valuable data for modelling and theoretical studies of aerosol–water interactions.
Abstract. This study reports a comprehensive dataset of oxygenated compounds, inorganic ions and other major aerosol constituents in fine particulate matter (2.5 μm) in the urban atmosphere of Hong Kong in periods of different synoptic weather conditions during 2003–05. The oxygenated compounds quantified include C2–C10 dicarboxylic acids, C3–C9 ketoacids and C2–C3 dicarbonyls, their combined concentrations accounting for 3.2–18.2% of water-soluble organic carbon on a carbon mass basis. Six C2 and C3 oxygenated compounds, namely oxalic acid, malonic acid, glyoxylic acid, pyruvic acid, glyoxal, and methyl glyoxal, dominate this suite of oxygenated compounds, accounting for 75% of the total quantified oxygenated species. Good correlations were observed among most of the quantified oxygenated compounds, suggesting that a relatively stable abundance distribution exists under varying synoptic conditions. These composition profiles provide a comprehensive dataset for use in modelling and theoretical studies of aerosol–water interactions, secondary aerosol formation pathways, and speciated organic mass distributions.
Additional keywords: oxalic acid, phthalic acid, secondary organic aerosols.
Acknowledgements
This work was partially supported by the Research Grants Council of Hong Kong, China (621708).
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