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Article     |     Next >>   Contents Vol 50(1)

Prediction of the CEC to clay ratio using mid-infrared spectroscopy

Philip M. Bloesch

Department of Environment and Resource Management, Ecosciences Precinct, Boggo Road, Dutton Park, Qld 4012, Australia. Email: Phil.Bloesch@derm.qld.gov.au

Soil Research 50(1) 1-6 http://dx.doi.org/10.1071/SR11137
Submitted: 10 June 2011  Accepted: 26 December 2011   Published: 13 February 2012


 
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Abstract

The ratio of cation exchange capacity to clay (CCR) has been used as an index of clay mineralogy in subsoils low in organic matter in place of the standard X-ray diffraction measurement. Laboratory determination of this ratio is time-consuming and expensive and involves two analyses. In this paper, the CCR has been successfully predicted from mid-infrared diffuse reflectance spectra using partial least-squares regression (PLSR) with a square-root transformation of the CCR values (R2 = 0.860; root mean squared error of prediction = 0.089; relative per cent deviation = 2.660 for an independent validation set). The most important wavelengths used in the PLSR calibration were identified. The prediction of CCR using mid-infrared spectroscopy provides a cheaper and faster alternative to laboratory determination.

Additional keywords: CEC to clay ratio, mid-infrared diffuse reflectance, partial least squares regression.


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