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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

A Novel 3D Salen Neodymium Framework with Near-Infrared (NIR) Properties

Shushen Chi A , Hongfeng Li A , Peng Chen A , Ting Gao A B C , Yu Yang A , Wenbin Sun A , Guangming Li A , Guangfeng Hou A and Pengfei Yan A C
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Functional Inorganic Material Chemistry (Ministry of Education), School of Chemistry and Materials Science, Heilongjiang University, No. 74, Xuefu Road, Nangang District, Harbin 150080, China.

B Key Laboratory of Chemical Engineering Process and Technology for High-Efficiency Conversion, College of Heilongjiang Province, No. 74, Xuefu Road, Nangang District, Harbin 150080, China.

C Corresponding authors. Email: gaotingmail@sina.cn; yanpf@vip.sina.com

Australian Journal of Chemistry 70(3) 265-270 https://doi.org/10.1071/CH16372
Submitted: 23 June 2016  Accepted: 25 July 2016   Published: 2 September 2016

Abstract

The reaction of N,N′-bis(3-hydroxy)ethylene-1,2-diamine (H2salen) with Nd(NO3)3·6H2O and NdCl3·6H2O yields a novel lanthanide complex, namely, Nd(salen)2(NO3)2Cl (1). X-ray crystallographic analysis revealed that H2salen effectively functions as a bridging ligand forming a kind of novel 3D structure complex which is constructed by Salen ligands and mixed lanthanide counter-ions without π–π stacking and hydrogen bond interactions. This is the first Salen-type 3D lanthanide complex to be constructed in this way. The near-infrared (NIR) properties of 1 in the solid state were also studied.


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