
TY  - JOUR
A1  - Bruce, Michael I. 
A1  - Skelton, Brian W. 
A1  - White, Allan H. 
A1  - Zaitseva, Natasha N. 
T1  - Crystal and Molecular Structures of Ru<emph tye="8">3</emph>(CO)<emph tye="8">12-n</emph>(PMe<emph tye="8">3</emph>)<emph tye="8">n</emph> <emph type="2">n</emph> = 1, 2)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1997
VL  - 50
IS  - 2
SP  - 163
EP  - 168
KW  - 
UR  - https://doi.org/10.1071/C96213 
N2  - The crystal and molecular structures of the title compounds are described. Both contain a triangular Ru3 core &#91;average Ru-Ru 2&#183;853 (n = 1), 2&#183;837 &#197; (n = 2)&#93;, with the PMe3 ligands occupying equatorial positions. For n = 2, substantial twisting about the Ru-Ru bonds results in one CO group adopting a semibridging position across the Ru-Ru vector joining a substituted Ru with the Ru(CO)4 fragment. Comparisons are also made with the previously determined n = 3 complex. 
ER  -

