
%0 Journal Article
%A Sobolev, Alexander N. 
%A Figgis, Brian N. 
%T Structures of Some Complexes Containing the Ru(NH<emph tye="8">3</emph>)<emph tye="8">6</emph><emph type="7">3+</emph> Unit
%J Australian Journal of Chemistry
%D 1997/10/14
%V 50
%N 8
%P 825-830
%K 
%R https://doi.org/10.1071/C96217
%U https://www.publish.csiro.au/paper/C96217 
%X The X-ray crystal structure determinations of three complexes of hexaammineruthenium(III) are reported. They are: (1) NH4+ .Ru(NH3)63+ .2ZnCl42&#175;, a 8&#183;566(2), c 12&#183;829(4) &#197;, V 941&#183;3(4) &#197;3,I 4/m, Z = 2, R1(2&#963;) = 0&#183;021, wR2 = 0&#183;054; (2) Ru(NH3)63+ .ZnCl4 2&#175;.Cl&#175;.H2O, a 8&#183;174(2), b 8&#183;979(2), c 10&#183;123(2) &#197;, &#945; 80&#183;20(2), &#946; 86&#183;41(2), &#947; 87&#183;23(2)&#176;, V 730&#183;2(3) &#197;3 , P-1, Z = 2, R1(2&#963;) = 0&#183;027, wR2 = 0&#183;074; (3) Ru(NH3)63+ .HgCl42&#175;.HgCl3&#175;.HgCl2.H2O, a 8&#183;055(3), b 21&#183;493(11), c 12&#183;625(4) &#197;, &#946; 90&#183;52(3)&#176;, V 2186(2) &#197;3 , P21/c, Z = 4, R1(2&#963;) = 0&#183;058, wR2 = 0&#183;142. The hexaammineruthenium(III) cations in these structures adopt differing conformations in respect of hydrogen atom disposition. Compounds (1) and (2) have disordered NH3 groups in the Ru(NH3)63+ cations, and in compound (1) the NH4+ cation is disordered as well. 
