
%0 Journal Article
%A Baker,, Robert W. 
%A Thomas,, George K. 
%A Rea, Simon O. 
%A Sargent, Melvyn V. 
%T Stereoselective Oxidation of Alkyl Azaheterocyclic Sulfides
%J Australian Journal of Chemistry
%D 1998/02/05
%V 50
%N 12
%P 1151-1158
%K 
%R https://doi.org/10.1071/C97061
%U https://www.publish.csiro.au/paper/C97061 
%X The asymmetric oxidation of prochiral sulfides in the presence of (4R,5R)-2,2-dimethyl-&#945;,&#945;,&#945;&#8242; ,&#945;&#8242;-tetraphenyl-1,3-dioxolan-4,5-dimethanol (1) has been investigated. The best results were obtained with 1-t-butylthioisoquinoline (4) as substrate and reasons for this observation are advanced. Circular dichroism spectroscopy allowed the absolute configurations of a number of alkyl azaheterocyclic sulfoxides to be proposed. 
