
TY  - JOUR
A1  - Baker,, Robert W. 
A1  - Thomas,, George K. 
A1  - Rea, Simon O. 
A1  - Sargent, Melvyn V. 
T1  - Stereoselective Oxidation of Alkyl Azaheterocyclic Sulfides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1998
VL  - 50
IS  - 12
SP  - 1151
EP  - 1158
KW  - 
UR  - https://doi.org/10.1071/C97061 
N2  - The asymmetric oxidation of prochiral sulfides in the presence of (4R,5R)-2,2-dimethyl-&#945;,&#945;,&#945;&#8242; ,&#945;&#8242;-tetraphenyl-1,3-dioxolan-4,5-dimethanol (1) has been investigated. The best results were obtained with 1-t-butylthioisoquinoline (4) as substrate and reasons for this observation are advanced. Circular dichroism spectroscopy allowed the absolute configurations of a number of alkyl azaheterocyclic sulfoxides to be proposed. 
ER  -

