
TY  - JOUR
A1  - Hartshorn, Chris M. 
A1  - Steel, Peter J. 
T1  - Serendipitous Isolation of a Trinuclear Silver Complex Containing a Bridging Tridentate Cyanide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1998
VL  - 50
IS  - 12
SP  - 1195
EP  - 1198
KW  - 
UR  - https://doi.org/10.1071/C97121 
N2  - The X-ray structure of a single crystal of a complex of formula C34H33Ag3N15O6 is described (P 21/c, Z4, a 10&#183;943(1), b 33&#183;873(5), c 10&#183;416(2) &#197;, &#946; 102&#183;54(1)&#176;, R 0&#183;0363). The asymmetric unit of this compound contains three silver atoms, two nitrate anions, a bridging tridentate cyanide ion, and one and a half molecules of the bridging tetrapodal ligand 1,2,4,5-tetrakis(pyrazol-1-ylmethyl)benzene. By virtue of the bridging nature of the ligand, these units further assemble into large macrocyclic rings, with a maximum dimension of &#62;24 &#197;. These rings then interlock to produce an intriguing two-dimensional metallopolymeric network. 
ER  -

