
TY  - JOUR
A1  - Lensink, Cornelis 
A1  - Gainsford, Graeme J. 
T1  - Synthesis and Structure of Two Isomers of Di(indenyl)phenylphosphine Sulfide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1998
VL  - 51
IS  - 8
SP  - 667
EP  - 672
KW  - 
UR  - https://doi.org/10.1071/C97210 
N2  - Dichlorophenylphosphine reacts with indenyllithium in tetrahydrofuran followed by sulfur to yield di(1H-inden-3-yl)phenylphosphine sulfide (2). The same reaction sequence in toluene yields di(1H-inden-1-yl)phenylphosphine sulfide (3) as a mixture of (&#177;) and two meso isomers. The structures of (2) and (&#177;)-(3) were determined &#91;(2): C24H19PS, Mr 370&#183;42, monoclinic, P21/n, a 14&#183;329(4), b 7&#183;0936(10), c 19&#183;405(5) &#197;, &#946; 99&#183;18(2)&#176;, Z 4, R 0&#183;060 for 2422 observed reflections; (3): C24H19PS, Mr 370&#183;42, monoclinic, P21/n, a 9&#183;521(5), b 16&#183;223(8), c 12&#183;930(6) &#197;, &#946; 107&#183;41(3)&#176;, Z 4, R 0&#183;105 for 923 reflections&#93;. 
ER  -

