
%0 Journal Article
%A Skelton, Brian W. 
%A Swiegers, Gerhard F. 
%A White, Allan H. 
%A Wild, S. Bruce 
%T A Diastereomer of an <emph type="2">ortho</emph>-Palladated <emph type="2">R</emph>)-&#945;-Methylbenzylamine Complex Containing an (<emph type="2">R</emph>,<emph type="2">R</emph>)-Tetra(tertiary phosphine) in Which the Two Organometallic Rings Have Opposite Helicities
%J Australian Journal of Chemistry
%D 1999/12/04
%V 51
%N 12
%P 1141-1148
%K 
%R https://doi.org/10.1071/C98104
%U https://www.publish.csiro.au/paper/C98104 
%X The bis(palladium(II)&#8211;(R)-a-methylbenzylamine) diastereomers of the (R*,R*)-(&#177;)-form of the lin- ear tetra(tertiary phosphine) 1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane, (RC)(RP,RP)- and (RC)(SP,SP)-(4), are readily separated because of a large difference in their solubilities in moderately polar solvents. The single-crystal X-ray structure of (RC)(SP,SP)-(4), along with published data on (RC)(RP,RP)-(4), suggests that the ease of separation is due to conformational differences in the two organometallic rings present in each diastereomer (&#948;&#948; or &#948;&lgr;) in the solid state. 
