
TY  - JOUR
A1  - Skelton, Brian W. 
A1  - Swiegers, Gerhard F. 
A1  - White, Allan H. 
A1  - Wild, S. Bruce 
T1  - A Diastereomer of an <emph type="2">ortho</emph>-Palladated <emph type="2">R</emph>)-&#945;-Methylbenzylamine Complex Containing an (<emph type="2">R</emph>,<emph type="2">R</emph>)-Tetra(tertiary phosphine) in Which the Two Organometallic Rings Have Opposite Helicities
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1999
VL  - 51
IS  - 12
SP  - 1141
EP  - 1148
KW  - 
UR  - https://doi.org/10.1071/C98104 
N2  - The bis(palladium(II)&#8211;(R)-a-methylbenzylamine) diastereomers of the (R*,R*)-(&#177;)-form of the lin- ear tetra(tertiary phosphine) 1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane, (RC)(RP,RP)- and (RC)(SP,SP)-(4), are readily separated because of a large difference in their solubilities in moderately polar solvents. The single-crystal X-ray structure of (RC)(SP,SP)-(4), along with published data on (RC)(RP,RP)-(4), suggests that the ease of separation is due to conformational differences in the two organometallic rings present in each diastereomer (&#948;&#948; or &#948;&lgr;) in the solid state. 
ER  -

