
%0 Journal Article
%A Smith, Graham 
%A Thomasson, Jon H. 
%A White, Jonathan M. 
%T Lewis Base Adducts of Silver(<emph type="6">I</emph>) <emph type="2">p</emph>-Toluenesulfonate. IV. The Preparation and Crystal Structures of the Complexes of Silver(<emph type="6">I</emph>) <emph type="2">p</emph>-Toluenesulfonate with 2,6-Diaminopyridine, Quinolin-8-ol, Hexane-1,6-diamine, and the Adduct of Hexane-1,6-diamine
%J Australian Journal of Chemistry
%D 1999/05/27
%V 52
%N 4
%P 317-324
%K 
%R https://doi.org/10.1071/C98127
%U https://www.publish.csiro.au/paper/C98127 
%X The reaction of silver(I) p-toluenesulfonate&#123;Ag(pts&#125; with a series of nitrogen bases has provided furtherexamples of adducts including one &#123;with 2,6-diaminopyridine (dap),&#91;&#123;Ag(pts)&#125; (dap)&#93;n (1)&#125; whichis a variant of the known polymeric adduct type&#91;&#123;Ag(pts)&#125;(L)m&#93;n,together with a second previously unreported complex type in which the ptsligand is displaced but remains as a counter anion&#91;Ag(L)m+&#93;.(pts-) &#91;withquinolin-8-ol (oxine), &#91;Ag(oxine)2+&#93;.(pts-) (2);hexane-1,6-diamine (dah),&#91;Ag2(dah)32+&#93;n.2n(pts-)(3)&#93;. Compound (1) is polymeric and is based on four-coordinate distortedtetrahedral AgN2O2 centres&#91;Ag&#123;N, 2&#183;249, 2&#183;326(2) &#197;; Ag&#8722;O,2&#183;491, 2 &#183;554(2) &#197;&#93;. Compound (2) comprises discreteAgN2O2 complex units in which theuncharged oxine ligands are asymmetric bidentate &#91;Ag&#8722;N,2&#183;208&#8722;2&#183;222(5) &#197;; Ag&#8722;O,2&#183;563&#8722;2&#183;597(5) &#197;&#93;. Compound (3) hasthree-coordinate silver centres with the metal coordinated to two dah ligandslinearly in a polymeric chain &#91;Ag&#8722;N, 2&#183;186, 2&#183;191(4)&#197;&#93;, with a third, longer interaction &#91;Ag&#8722;N,2&#183;494(4) &#197;&#93; completing a T-shaped coordination. In addition,the structure of the adduct of AgClO4 withhexane-1,6-diamine&#123;&#91;Ag(dah)+&#93;n&#183;n(ClO4&#8722;)&#125;(4) has been determined, and is polymeric, comprising classicalcentrosymmetric linear AgN2 coordination&#91;Ag&#8722;N, 2&#183;121(3) &#197;&#93; with only weakhydrogen-bonding interactions to the perchlorate 
