
%0 Journal Article
%A Miller, David J. 
%A Moody, Christopher J. 
%A Morffitt, C. Neil 
%T Diastereoselectivity in the O&#8211;H Insertion Reactions of Carbenoids Derived from Phenyldiazoacetates of Chiral Alcohols. II.  Comparison of Rhodium(<emph type="6">II</emph>)- and Acid-Mediated Reactions
%J Australian Journal of Chemistry
%D 1999/02/19
%V 52
%N 2
%P 97-108
%K 
%R https://doi.org/10.1071/C98159
%U https://www.publish.csiro.au/paper/C98159 
%X Rhodium(II)- or acid-mediated decomposition of 2-diazo-2-phenylacetates of chiral alcohols in the presence of various hydroxylic compounds (ROH) results in the diastereoselective formation of 2- hydroxy-, 2-alkoxy- or 2-trialkylsiloxy-2-phenylacetates, with the acid-mediated process giving the higher diastereoselectivity. 
