
TY  - JOUR
A1  - Baker, Murray V. 
A1  - Palermo, Maria C. 
A1  - Skelton, Brian W. 
A1  - White, Allan H. 
T1  - Titanium(<emph type="6">IV</emph>) Imido Complexes of 1,3,5-Trialkyl-1,3,5-triazacyclohexanes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1999
VL  - 52
IS  - 3
SP  - 179
EP  - 184
KW  - 
UR  - https://doi.org/10.1071/C98173 
N2  - Reactions of the imido complex Ti(NBut)Cl2(py)3 (py = pyridine) with 1,3,5-trialkyl-1,3,5-triazacyclo- hexanes (R3tach) produce the corresponding imido complexes TiCl2(NBut)(R3tach) (R = Et, But). The new complexes have been characterized by n.m.r. spectroscopy and, for the R = Bu t case, by X-ray diffraction studies. The absence of a C3v axis of symmetry for the new complexes allowed complete and unequivocal assignment of their 1H n.m.r. spectra by consideration of proton&#123;proton coupling and nuclear Overhauser effects. 
ER  -

