
%0 Journal Article
%A Hambley, Trevor W. 
%A Frankcombe, Katrina E. 
%A Yates, Brian F. 
%A Cavell, Kingsley J. 
%A Knott, Robert B. 
%T The Structure of a Methylpalladium(II) Complex of Pyridine-2-carboxylato (N&#8211;O) and Triphenylphosphine (PPh<emph type="8">3</emph>), [Pd(CH<emph type="8">3</emph>)(N&#8211;O)(PPh<emph type="8">3</emph>)]
%J Australian Journal of Chemistry
%D 2000/12/22
%V 53
%N 9
%P 805-807
%K Palladium, picolinic acid; X-ray crystal structure.
%R https://doi.org/10.1071/CH00064
%U https://www.publish.csiro.au/paper/CH00064 
%X The compound &#91;Pd(CH3)(PPh3)(N&#8211;O)&#93; (N&#8211;O represents pyridine-2-carboxylato (pyca)) has been synthesized and the structure determined. The compound crystallized in the monoclinic space group P21/c, a 8.4844(9), b 12.845(2), c 19.690(3) &#197;, b 92.09(1)&#x02DA;, V 2144.4(5) &#197; 3 , Z 4, and was refined to an R value of 0.022 on 3551 F. The structure had a distorted square-planar geometry in which the donor nitrogen and phosphine ligands are trans. 
