
TY  - JOUR
A1  - Hambley, Trevor W. 
A1  - Frankcombe, Katrina E. 
A1  - Yates, Brian F. 
A1  - Cavell, Kingsley J. 
A1  - Knott, Robert B. 
T1  - The Structure of a Methylpalladium(II) Complex of Pyridine-2-carboxylato (N&#8211;O) and Triphenylphosphine (PPh<emph type="8">3</emph>), [Pd(CH<emph type="8">3</emph>)(N&#8211;O)(PPh<emph type="8">3</emph>)]
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2000
VL  - 53
IS  - 9
SP  - 805
EP  - 807
KW  - Palladium, picolinic acid; X-ray crystal structure.
UR  - https://doi.org/10.1071/CH00064 
N2  - The compound &#91;Pd(CH3)(PPh3)(N&#8211;O)&#93; (N&#8211;O represents pyridine-2-carboxylato (pyca)) has been synthesized and the structure determined. The compound crystallized in the monoclinic space group P21/c, a 8.4844(9), b 12.845(2), c 19.690(3) &#197;, b 92.09(1)&#x02DA;, V 2144.4(5) &#197; 3 , Z 4, and was refined to an R value of 0.022 on 3551 F. The structure had a distorted square-planar geometry in which the donor nitrogen and phosphine ligands are trans. 
ER  -

