
%0 Journal Article
%A Freire, Eleonora 
%A Baggio, Sergio 
%A Suescun, Leopoldo 
%A Baggio, Ricardo 
%T X-Ray Study of Two Novel Nickel(II)&#8211;Thiosulfate Compounds
%J Australian Journal of Chemistry
%D 2000/12/22
%V 53
%N 9
%P 785-790
%K Bridging thiosulfate; five-coordinate nickel.
%R https://doi.org/10.1071/CH00108
%U https://www.publish.csiro.au/paper/CH00108 
%X Two novel nickel thiosulfate complexes have been prepared and their crystal structures determined: NiS2O3(dmph)(H2O)&#183;H2O&#183;CH3OH (1) (dmph = 2,9-dimethyl-1,10-phenanthroline), which to our knowledge is the first pentacoordinated nickel thiosulfate complex described so far, and NiS2O3(dmph) (2), a hexacoordinated complex which displays a thiosulfate binding mode with no precedents in the literature, viz. bridging solely through oxygen. Compound (1) is monoclinic, C2/c, a 26.269(5), b 7.641(3), c 18.381(3) &#197;, &#946; 97.00(2)&#x02DA;, V 3662(2) &#197; 3 ,Z 8, conventional R (on F) being 0.049 for 2217 No observed reflections (I &#62; 2&#963;(I)). Compound (2) is also monoclinic, P21/n, a 11.108(2), b 10.955(2), c 11.666(2) &#197;, &#946; 103.32(3)&#x02DA;, V 1381.4(5) &#197; 3 , Z 4, R 0.036, No 2497. 
