
TY  - JOUR
A1  - Freire, Eleonora 
A1  - Baggio, Sergio 
A1  - Suescun, Leopoldo 
A1  - Baggio, Ricardo 
T1  - X-Ray Study of Two Novel Nickel(II)&#8211;Thiosulfate Compounds
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2000
VL  - 53
IS  - 9
SP  - 785
EP  - 790
KW  - Bridging thiosulfate; five-coordinate nickel.
UR  - https://doi.org/10.1071/CH00108 
N2  - Two novel nickel thiosulfate complexes have been prepared and their crystal structures determined: NiS2O3(dmph)(H2O)&#183;H2O&#183;CH3OH (1) (dmph = 2,9-dimethyl-1,10-phenanthroline), which to our knowledge is the first pentacoordinated nickel thiosulfate complex described so far, and NiS2O3(dmph) (2), a hexacoordinated complex which displays a thiosulfate binding mode with no precedents in the literature, viz. bridging solely through oxygen. Compound (1) is monoclinic, C2/c, a 26.269(5), b 7.641(3), c 18.381(3) &#197;, &#946; 97.00(2)&#x02DA;, V 3662(2) &#197; 3 ,Z 8, conventional R (on F) being 0.049 for 2217 No observed reflections (I &#62; 2&#963;(I)). Compound (2) is also monoclinic, P21/n, a 11.108(2), b 10.955(2), c 11.666(2) &#197;, &#946; 103.32(3)&#x02DA;, V 1381.4(5) &#197; 3 , Z 4, R 0.036, No 2497. 
ER  -

