
TY  - JOUR
A1  - Fairweather, Jon K. 
A1  - Stick, Robert V. 
A1  - Withers, Stephen G. 
T1  - A 'Glycosynthase'-assisted Synthesis of Some Epoxyalkyl &#946;-<emph type="2">C</emph>-Oligosaccharides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2001
VL  - 53
IS  - 12
SP  - 913
EP  - 916
KW  - Glucopyranosides; oligosaccharides; epoxyalkyl oligosaccharides; &lsquor; &#946;-glycan hydrolases.
UR  - https://doi.org/10.1071/CH00125 
N2  - A series of alkenyl &#946;-D-C-glucopyranosides has been glycosylated with &#945;-D-glucopyranosyl fluoride in a &#8216;Glycosynthase&#8217; reaction to yield a range of alkenyl  &#946;-C-cellobiosides and -triosides and in one case a -C-cellotetraoside. Conversion of some of the alkenyl &#946; -D-C-oligosaccharide products into their corresponding epoxides and subsequent deprotection under standard conditions have afforded a panel of epoxyalkyl &#946; -C-oligosaccharides for evaluation as inhibitors of retaining &#946;-glycan hydrolases. 
ER  -

