
%0 Journal Article
%A Harvey, Miguel Angel 
%A Baggio, Sergio 
%A Garland, María Teresa 
%A Burton, Gerardo 
%A Baggio, Ricardo 
%T Structural Studies on Complexes Containing the Peroxodisulfate Anion. I The Crystal and Molecular Structure of Cd(pds)(phen)<emph type="8">2</emph>(H<emph type="8">2</emph>O)&#183;H<emph type="8">2</emph>O and Cd(pds)(dmph)<emph type="8">2</emph> &#91;pds = Peroxodisulfate (S<emph type="8">2</emph>O<emph type="8">8</emph> <emph type="7">2&#8211;</emph>); phen = 1,10-Phenanthroline; dmph = 2,9-Dimethyl-1,10-phenanthroline&#93;
%J Australian Journal of Chemistry
%D 2001/11/29
%V 54
%N 5
%P 307-311
%K 
%R https://doi.org/10.1071/CH01078
%U https://www.publish.csiro.au/paper/CH01078 
%X The crystal structures of two unreported CdII complexes with different dinitrogenated bases and the unusual peroxodisulfate anion (pds, S2O8 2&#8211;) are presented: Cd(pds)(phen)2(H2O)&#183;H2O and Cd(pds)(dmph)2 (phen = 1,10- phenanthroline; dmph = 2,9-dimethyl-1,10-phenanthroline). Both compounds are monomeric. In the first, the anion acts as a monodentate ligand, as in all previously reported structures where it binds to a cation, while in the second it displays novel chelate behaviour. Both structures are stabilized by hydrogen-bonding networks, with mediumstrength interactions mediated by aqua and hydration water molecules in the first case and much weaker ones provided by C&#8211;H&hellip;O contacts in the second. Compound (1) is triclinic, P1&#8211;, a 8.745(3), b 9.260(5), c 17.564(3) &#197;, &#945; 96.80(2), &#946; 101.581(3), &#947; 105.97(3)&#x02DA;, V 1316.6(9) &#197;3, Z 2, R 0.044, No 4384. Compound (2) is monoclinic, Cc, a 22.233(12), b 9.566(5), c16.017(8) &#197;, &#946; 123.78(3)&#x02DA;, V2831(3) &#197;3, Z 4, R 0.024, No 2363. 
