
TY  - JOUR
A1  - Bruce, Michael I. 
A1  - Meier, Andrew C. 
A1  - Skelton, Brian W. 
A1  - White, Allan H. 
A1  - Zaitseva, Natasha N. 
T1  - Some Ruthenium Cluster Chemistry with Alkynes: Structures of Two Ru<emph type="8">3</emph> and Two Ru<emph type="8">4</emph> Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2001
VL  - 54
IS  - 5
SP  - 319
EP  - 324
KW  - 
UR  - https://doi.org/10.1071/CH01079 
N2  - The molecular structures of four ruthenium cluster complexes, isolated in small amounts in the course of studies of the reactions of alkynes or a 1,3-diyne with ruthenium cluster carbonyls, are reported: Ru3(&#181;3-PhC2C=CHPh)(&#181;- OH)(CO)9 (1), from Ru3(CO)10(NCMe)2and PhC&#197;&fllig;CC&#197;&fllig;CPh, is probably formed by addition of water to a diyne&#8211; Ru3 precursor; Ru3&#123;&#181;3-C(OCH2CH=CH2)CHCCPh2OC(O)&#125;(&#181;-dppm)(&#181;-CO)(CO)6 (2) was isolated from the many products of the reaction between Ru3(&#181;&#8722;dppm)(CO)10and HC&#197;&fllig;CCPh2(OH); Ru4(&#181;4-PhCHC2CHPh)(CO)12 (3) was found among the thermolysis products of Co2Ru3(&#181;5-PhC2C2Ph)(&#181;-CO)3(CO)11; and Ru4(&#181;4-CHCCH2- CHPMe3)(CO)10(PMe3) (4) was formed by reaction of PMe3 with Ru3(&#181;3-HC2H)(&#181;-CO)(CO)9. 
ER  -

