
TY  - JOUR
A1  - Funston, A. M. 
A1  - McFadyen, W. D. 
A1  - Tregloan, P. A. 
T1  - The Synthesis and Crystal Structures of Two Cobalt(III) Complexes Containing the Ligand 1,4,8,11-Tetraazacyclotetradecane
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2002
VL  - 55
IS  - 8
SP  - 535
EP  - 538
KW  - 
UR  - https://doi.org/10.1071/CH02015 
N2  - The new cobalt(III) complex [Co(cyclam)(NO3)2]NO3·HNO3 (2) has been synthesized. The crystal structure of this complex and the related complex [Co(cyclam)(NH3)2]Cl2BF4·2H2O (1) have been determined. Crystal data for (1): M 451.04, monoclinic, space group P21/c (No. 14), a 7.3927(10), b 13.3082(7), c 19.524(2) &#197;, &#946; 97.625(14)°, V 1903.9(3) &#197;3, F(000) 936, Z 4, Dc 1.574 g cm&#8211;3, &#956; 1.225 cm&#8211;1, Mo K&#945; (graphite monochromatized) &#955; 0.71073 &#197;, T 293(1) K. Crystal data for (2): M 571.33, triclinic, space group P1&#8211;(No. 2),a 7.3988(14), b 8.5682(16), c 9.209(3) &#197;, &#945; 89.02(2), &#946; 76.64(3), &#947; 82.340(16)°, V 562.9(2) &#197;3, F(000) 296, Z 1, Dc 1.685 g cm&#8211;3, &#956; 0.854 cm&#8211;1, Mo K&#945; (graphite monochromatized) &#955; 0.71073 &#197;, T 293(1) K. In both complexes the complex crystallizes in the trans-III form with the cobalt in the usual octahedral environment. 
ER  -

