
%0 Journal Article
%A Bennett, M. A. 
%A Bhargava, S. K. 
%A Mohr, F. 
%A Welling, L. L. 
%A Willis, A. C. 
%T Synthesis and X-Ray Structure of a Heterovalent, Cycloaurated Pentafluorophenylgold(I)/Pentafluorophenylgold(III) Complex
%J Australian Journal of Chemistry
%D 2002/07/09
%V 55
%N 4
%P 267-270
%K 
%R https://doi.org/10.1071/CH02034
%U https://www.publish.csiro.au/paper/CH02034 
%X The heterovalent gold(I)/gold(III) complex [(C6F5)AuI(&#956;-2-Ph2PC6H3-6-Me)AuIII(C6F5){&#951;2-(6-MeC6H3-2-PPh2)}] has been prepared and structurally characterized by X-ray crystallography. It shows square planar stereochemistry at AuIII incorporating a four-membered chelate ring and linear arrangement at AuI. The compound is a rare example of a heterovalent complex containing an aryl ligand on each gold atom. 
