
%0 Journal Article
%A Russell, G. T. 
%T The Kinetics of Free-Radical Polymerization: Fundamental Aspects
%J Australian Journal of Chemistry
%D 2002/09/19
%V 55
%N 7
%P 399-414
%K 
%R https://doi.org/10.1071/CH02114
%U https://www.publish.csiro.au/paper/CH02114 
%X Some fundamental aspects of the kinetics of free-radical polymerization are reviewed. So-called classical results for rate and molecular-weight distribution are first of all presented. It is shown how this approach can be built upon when chain-length-dependent termination is allowed, which it always should be. Various termination models are considered, and it is illustrated that although the models are different, rather remarkably they give common, model-independent behaviour. Some leading experimental results regarding the chain-length dependence of termination are summarized, before the chain-length dependence of other reactivities, the variation of reactivities with conversion, and non-steady state experiments are briefly discussed. Finally, living free-radical polymerization as effected by a reversible termination agent is considered. An outline of the kinetics of these systems is given, with the oft-neglected importance of conventional termination being stressed. 
