
%0 Journal Article
%A Othman, A. Hamid bin 
%A Skelton, Brian W. 
%A White, Allan H. 
%T Synthesis and Structure of the Binuclear 1 : 1 Silver(<emph type="6">I</emph>) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex
%J Australian Journal of Chemistry
%D 2003/06/30
%V 56
%N 7
%P 718-721
%K 
%R https://doi.org/10.1071/CH02135
%U https://www.publish.csiro.au/paper/CH02135 
%X A room-temperature single-crystal X-ray structure determination of the 1 : 1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(&#956;-O)2Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen. 
