
TY  - JOUR
A1  - Othman, A. Hamid bin 
A1  - Skelton, Brian W. 
A1  - White, Allan H. 
T1  - Synthesis and Structure of the Binuclear 1 : 1 Silver(<emph type="6">I</emph>) 2-Hydroxy-3,5-dinitrobenzoate/Triphenylphosphine Complex
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2003
VL  - 56
IS  - 7
SP  - 718
EP  - 721
KW  - 
UR  - https://doi.org/10.1071/CH02135 
N2  - A room-temperature single-crystal X-ray structure determination of the 1 : 1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(&#956;-O)2Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen. 
ER  -

