
TY  - JOUR
A1  - Henry, David J. 
A1  - Beckwith, Athelstan L. J. 
A1  - Radom, Leo 
T1  - Homoanomeric Effect in the 1,2-Dimethoxyethyl Radical
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2003
VL  - 56
IS  - 5
SP  - 429
EP  - 436
KW  - 
UR  - https://doi.org/10.1071/CH02255 
N2  - A homoanomeric effect is found to stabilize the 1,2-dimethoxyethyl radical (CH3O&#8211;&#x010A;H&#8211;CH2OCH3) in a conformation in which the singly-occupied orbital at the radical centre is approximately coplanar with the p-type lone pair on the &#945;-oxygen and with the &#946;-C&#8211;O bond. The magnitude of this stabilization is predicted to be &#126;10&#8211;12 kJ mol&minus;1 at the G3(MP2)-RAD and CBS-RAD levels of theory. 
ER  -

