
TY  - JOUR
A1  - Schröder, Detlef 
A1  - Soldi-Lose, Héloïse 
A1  - Schwarz, Helmut 
T1  - Unimolecular Rearrangements of Transient Carboxy Radicals and Cations
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2003
VL  - 56
IS  - 5
SP  - 443
EP  - 451
KW  - 
UR  - https://doi.org/10.1071/CH02265 
N2  - Charge reversal (CR) and neutralization&#8211;reionization (NR) mass spectra of aliphatic carboxylate ions RCOO&#8211; provide insight into the behaviour of the transient neutral carboxy radicals RCOO&#8226; as well as the short-lived RCOO+ cations. For the neutral radicals, a novel hydrogen rearrangement is proposed, which might explain the sometimes only modest yields in the Hunsdiecker reaction of carboxylic acids in the condensed phase. 
ER  -

