
TY  - JOUR
A1  - Yang, Jin-Hua 
A1  - Li, Wei 
A1  - Zheng, Shao-Liang 
A1  - Huang, Zhen-Li 
A1  - Chen, Xiao-Ming 
T1  - A Two-Dimensional Layered Cadmium Polymer Featuring Cd<emph type="8">4</emph>(&#956;-O)<emph type="8">4</emph> Cores and Fluorescent Emission
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2003
VL  - 56
IS  - 12
SP  - 1175
EP  - 1178
KW  - 
UR  - https://doi.org/10.1071/CH03195 
N2  - A cadmium coordination complex featuring novel Cd4(&#956;-O)4 cores, [Cd2(Hbna)(opy)(H2O)2] (1) (H4bna=2,2&#8242;-dihydroxy-[1,1&#8242;]-binaphthalene-3,3&#8242;-dicarboxylate acid; Hopy=1H-pyridine-2-one), has been hydrothermally synthesized and characterized. The Hbna ligand here acts in an unprecedented chelating/tridentate coordination mode for two carboxy groups with an additional &#956;-O-bridging coordination mode for the ortho-hydroxy oxygen atom. A study of the physical properties of solid (1) at room temperature demonstrates that it exhibits a moderately strong fluorescent emission in the blue-green region (about 538 nm), which can be assigned to LMCT emission. 
ER  -

