
TY  - JOUR
A1  - Johnson, James E. 
A1  - Canseco, Diana C. 
A1  - Rowe, Jeffrey E. 
T1  - The Preparation of Methyl (<emph type="3">E</emph>)- and (<emph type="3">Z</emph>)-<emph type="3">O</emph>-Methylbenzothiohydroximates
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2004
VL  - 57
IS  - 6
SP  - 549
EP  - 552
KW  - 
UR  - https://doi.org/10.1071/CH03218 
N2  - A series of methyl (Z)-O-methylbenzothiohydroximates were prepared either by reaction of the corresponding (Z)-N-methoxybenzenecarboximidoyl bromides with potassium fluoride in dimethyl sulfoxide, or by reaction of N-methoxybenzamides with Lawesson&#8217;s reagent followed by alkylation. Irradiation of the Z isomers led to a photostationary equilibrium containing mixtures of approx. 40% E and 60% Z, from which the E isomers were isolated. 
ER  -

